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| Name: | Lithium AA Battery (FR14505) |
| Battery Type: | Small Size AA Battery - Non-Rechargeable |
| Battery Model Ref: | AA (FR14505) |
| Nominal Voltage: | 1.5V |
| Rated Capacity: | 3000mAh |
| Lithium Content: | 0.9g |
| Weight: | 15.5g |
| Size: | 14.0mm x 50.5mm |
| Prepared by: | ZENOX Energy Company Limited |
Primary Route of Exposure: Eyes, skin contact, ingestion.
Health Hazard: The batteries are not hazardous when used according to the instructions of manufacturer under normal conditions. In case of abuse, there’s a Hazard of rupture, fire, heat, leakage of internal components, which could cause casualty loss. Abuses including but not limited to the following cases: charged for a long time, short circuited, put into fire, whacked with hard object, punctured with acute object, crushed, and broken.
| Chemical Name | Concentration % | CAS Number |
|---|---|---|
| Iron | 35.7 | 7439-89-6 |
| Iron Sulfide Compound | 30.6 | 1317-37-9 |
| Polypropylene | 2.5 | 9003-07-0 |
| Organic Solvent | 14.8 | confidential |
| Lithium Salt | 1.9 | 63676-96-0 |
| Lithium | 6.4 | 7439-93-2 |
| Aluminum | 8.1 | 7429-90-5 |
| Cadmium | 0 (not detected) | 7440-43-9 |
| Mercury | 0 (not detected) | 7439-97-6 |
Notes: Labelling according to EC Directives. No Symbol and Hazard Phrase required. CAS = Chemical Abstract Service Registry Number.
| Eye contact: | Immediately flush eye with plenty of clean water for at least 15 minutes. Seek medical attention. |
| Skin contact: | Immediately flush skin with plenty of clean running water for at least 15 minutes. Remove contaminated clothes. Seek medical attention. |
| Inhalation: | Immediately move to fresh air. If necessary administer oxygen. Seek medical attention. |
| Ingestion: | Do not induce vomiting or give food or drink. Seek medical attention immediately. |
Lithium-X (Class D extinguishing media) and dried sand are effective extinguishing media on fires involving lithium batteries.
| Characteristics of Hazard: | Dusts at sufficient concentrations can form explosive mixtures with air. Combustion generates toxic fumes. |
| Hazardous Combustion Products: | Carbon Dioxide |
| Fire Extinguishing Methods & Media: | For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Lithium-X (Class D extinguishing media) and dried sand are effective media on lithium battery fires. |
| Attention to Fire-extinguishing: | Wear self-contained breathing apparatus in pressure-demand, MSHA/NIOSH approved and full protective gear. |
| Personal Precautions, Protective Equipment and Emergency Procedures: | In case of rupture. Attention! Corrosive material. Avoid contact with skin, eyes and clothing. Always ensure adequate ventilation. Always use protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spills/leaks. Under abusive conditions, the battery contained materials may leak. Always put leaked batteries into small containers or plastic bags, adding neutralising agents of sodium carbonate (Na2CO3), chalk (CaCO3) or lime (CaO) powder. |
| Environmental Precautions: | Always prevent the products from contaminating soil and from entering sewers or waterways. |
| Methods and Materials for Containment: | Stop the leak if safe to do so. Contain the spilled liquid with dry sand or earth. Clean up spills immediately. |
| Method and Materials for Cleaning Up: | Absorb spilled material with an inert absorbent (dry sand or earth). Scoop contaminated absorbent into an acceptable waste container. Always use appropriate protective equipment. Collect all contaminated absorbent and dispose of according to the directions in Section 13. Scrub area with detergent and water and collect all contaminated wash water for proper disposal. |
| Handling: | The battery may explode or cause burns if disassembled, crushed, exposed to fire or high temperatures or abused in any way. Do NOT short or install with incorrect polarity. |
| Storage: | Store in a cool, dry, well ventilated area away from incompatible substances. Store locked up and keep out of reach of children. |
| Other Precautions: | In case of rupture. Handle in accordance with good industrial hygiene and safety practices. Avoid contact with skin, eyes or clothing. Use personal protection equipment. |
| Engineering Controls: | Use adequate ventilation at all times to keep airborne concentrations low. If used under conditions that generate particulates, the ACGIH TLV-TWA of 3mg/m³ respirable fraction (10mg/m³ total) should be observed. |
| Eye and Face Protection: | None required for consumer use. If there is a hazard of, or potential hazard of contact, always wear tightly seal-able safety goggles and a face protection shield. |
| Skin and Body Protection: | None required for consumer use. If there is a hazard of, or potential hazard of contact, always wear tightly saleable safety goggles and a face protection shield. In case of leakage, wear protective gloves. |
| Respiratory Protection: | No protective equipment is required under normal use conditions. If exposure limits are exceeded or irritation is experienced, immediate ventilation and evacuation may be required. Also, as in the case of any fire situation, use self-contained breathing apparatus to protect respiration. In the event of leakages, wear protective chemical apron. |
| Physical State: | Appearance: | Cylindrical. Solid. |
| Colour: | Black/Orange. | |
| Odour: | If leaked, smells of pungent corrosive odour, sometimes medical ether. | |
| Condition Change: | pH: | Not Applicable as supplied. |
| Flash Point: | Not Applicable unless individual components exposed. | |
| Flammability: | Not Applicable unless individual components exposed. | |
| Relative Density: | Not Applicable unless individual components exposed. | |
| Solubility (water): | Not Applicable unless individual components exposed. | |
| Solubility (other): | Not Applicable unless individual components exposed. |
| Chemical Stability: | Stable under recommended storage conditions. |
| Possibility of Hazardous Reactions: | None under normal processing. |
| Conditions to Avoid: | Exposure to air or moisture over prolonged periods. Avoid force, dropping, crushing, disassembling, short-circuiting, re-changing, fire & heat above 100°C, incineration. |
| Incompatible Materials: | Acids, Oxidizing agents, Bases. |
| Hazardous Decomposition Products: | Carbon Oxides. Reaction of lithium metal with water: Hydrogen (H2)/Lithium Oxide (Li2O) and Lithium Hydroxide (Al(OH)3). |
| Irritation: | In the event of exposure to internal contents, vapour fumes may be very irritating to the eyes and skin. May cause redness, tearing, burns to eye and skin and irritation to respiratory system. Medical conditions generally aggravated by exposure: Eczema, skin allergies, lung injuries, asthma, other respiratory disorders. |
| Sensitization: | Not Available. |
| Reproductive Toxicity: | Not Available |
| Toxicologically Synergistic Materials: | Not Available. |
| General Note 1: | Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage systems. |
| Anticipated behaviour of a chemical product in environment/possible environmental impact/ecotoxicity: | Not Available. |
| Waste Treatment: | Recycle or dispose of in accordance with government, state and local regulations. |
| Important Note 1 - Attention for waste disposal: | Deserted batteries should not be treated as ordinary waste. They should NOT be thrown into fires or placed in high temperatures. They should NOT be dissected, pierced or crushed. |
| Important Note 2: | Deserted batteries should only be disposed of/cycled by and at permitted waste disposal treatment sites. |
| UN Number: | UN 3090 |
| UN3090: | Lithium Metal Batteries |
| Note 1: | Lithium metal cells and batteries are considered as Dangerous Goods with UN3090 and/or UN3091. |
| Note 2: | Depending on the lithium metal content, some cells or batteries may be regarded as non-dangerous goods without Class 9 nomination. |
| Shipping Name: | Lithium metal batteries (including lithium alloy batteries) |
| Labels/Placard Required: | Lithium Batteries Mark, Class 9 Hazard Label, Cargo Aircraft Only Label. |
| ICAO/IATA: | Can be shipped by air in accordance with International Civicl Aviation Organisation (ICAO), TI or International Air Transport Association (IATA), DGR Packing Instructions (PI) 968 Section 1B appropriate of IATA DGR 64th (2023 Edition) for transportation. |
| IMDG CODE: | The batteries are not restricted to IMDG Code 2020 Edition (Amdt 40-20) according to special provision 188. |
| DOT: | Other requirements for US Department of Transportation (DOT) SubChapter C, Hazardous Materials Regulations if shipped in compliance with 49 CFR 173.185. |
| ADR/ADN: | The batteries are not subject to the provisions of the United Nations Economic Commission for Europe (UNECE) ADR/AND if they meet the requirements of special provision 188 of Chapter 3.3, applicable as from 1st January 2023. |
| Note 1: | In addition, to be permitted in transport each lithium cell and battery types must have passed the applicable tests set out in Subsection 38.3 of the UN Manual of Tests and Criteria. |
Relevant Regulations and References:
MSDS Creation Date: 2023 Version: 1.0
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Allthough certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Disclaimer: The information listed in this document is, to the best of our belief and knowledge, accurate as at the date publishing. However, neither ZENOX Energy Ltd or any of its subsidiaries, suppliers, contractors, partners or employees, assumes or accepts any liability whatsoever for the accuracy or completeness of the information contained herein.
Final consideration of suitability of any materials or applications is the sole responsibility of the user.
All materials may present unknown hazards and should be used with caution. Known hazards are described herein, but these should not be assumed to be exhaustive.
Singapore Branch Office:
ZENOX ® Energy Limited
Level 42, 6 Battery Road
Singapore 049909
Singapore
Dubai Branch Office:
ZENOX ® Energy Limited
Building C3,
Dubai World Trade Centre (DWTC),
Sheikh Zayed Road, PO Box 9573,
00000, Dubai,
United Arab Emirates
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